Germicidal dental floss

ABSTRACT

A germicidal dental floss having a coating of the active material typically a phenol derivative/compound removably fixed thereon by a binder such as wax. The active material is rubbed off by contact with the teeth thereby treating areas between the teeth and gums for improved oral hygiene.

The present Application is a third Continuation-In-Part Application ofSer. No. 07/741,585, filed on Aug. 7, 1991 now U.S. Pat. No. 5,174,313,which was a second Continuation-In-Part Application of Ser. No.07/459,181, filed on Dec. 29, 1989 which granted to U.S. Pat. No.5,040,554 on Aug. 20, 1991 which was a first Continuation-In-Part ofApplication of Ser. No. 07/243,621, filed on Sep. 13, 1988, which hasbeen abandoned, but for which there has been maintained a continuouschain of copendency.

BACKGROUND OF THE INVENTION

This invention relates generally to an improved dental floss of theantibacterial/analgesic type, and, more specifically to a germicidaldental floss and a process for making same.

The art to which this invention relates of which applicant is alreadyaware, includes the following U.S. Pat. Nos. 719,017; 3,830,247,3,342,539.

The first of these describe the combination with a toothpick of a holderhaving a discharging duct, a handle having a reservoir of antisepticliquid, a reciprocating plunger for expelling liquid through the ductand onto the toothpick for discharging antiseptic between and at theroots of teeth while also picking the teeth. U.S. Pat. No. 3,830,247discloses dental floss impregnated with antiseptic in a housingtherefore wherein the floss passes through a reservoir of antiseptic.U.S. Pat. No. 3,342,539 teaches a dental floss which comprises a lengthof conventional construction terminating in a porous section which whenpre-soaked prior to use, in an antiseptic solution, then delivered intointerdental spaces as the floss is used normally to physically removefood particles from between the teeth.

Applicant is also aware of U.S. Pat. Nos. 2,667,443; 3,838,702;3,897,795; and 4,029,113.

U.S. Pat. No. 2,667,443 teaches the impregnation of dental floss both bydry, waxborn and resin bound carriers with therapeutic, cleaning agentsor medicaments.

U.S. Pat. No. 3,838,702 teaches a dental floss having an improvedcleaning and polishing action obtained by coating the floss with acoating agent comprising a resilient wax, polymer or elastomer, havingembedded therein a finely divided, particulate, polishing agent. Inaddition, the incorporation of various adjuvant materials into thecoating agent such as coloring matter, flavoring, medicinals ortherapeutic agents is suggested.

U.S Pat. No. 3,897,795 teaches that binding or coating floss fibers withwax is unsuitable where bacterially active matter is to be incorporatedin the floss, as wax coating resisted or repelled water and provided anindifferent binder for solids, directing instead the use of a soap ordetergent binder in which bacterially active matter can besimultaneously bonded or impregnated in the floss fibers. Theapplication may take place through using squeegees and/or squeegeerollers, by using a volatile ingredient as a solvent for the activeagent and/or binder or by pulling the floss through a paste mix of theactive agent.

U.S. Pat. No. 4,029,113 teaches a waxed dental textile material having afluorine compound distributed through the wax coating which providesfluoride iron in a therapeutic amount to inhibit the formation of dentalcavities.

As will be seen hereinafter, none of these disclose applicant's novel,unique and unobvious product and process which overcomes the prejudiceof the prior art against using a wax binder or coating for floss wherebacterially active matter is incorporated in the floss.

SUMMARY OF THE INVENTION

In its product aspect, this invention resides in a dental floss coatedwith a microcrystalline wax containing a prophylactic, antimicrobialanalgesic and/or antiseptic material.

More particularly, the invention concerns a prophylactic dental flosscomprising a flexible length of floss having at least on the exteriorthereof a coating of a phenol derivative/compound germicidal materialtypically selected from the group of synonyms generally known andconsisting of 4-hexylresorcinol; or 1,3-benzenediol,-4-hexyl oralternatively sodium phenolate and a binder removably securing saidmaterial to said length of floss. The coating may include from 0.001 to25 percent by weight of said germicidal material, the remainder of thecoating being said binder.

When a high degree of sepsis is present a coating from 25 to 75 percentby weight of germicidal material, may be more beneficial.

In a particularly advantageous form, the coating includes4-hexylrescorcinol in an analgesic combination, preferably 25 to 75percent by weight of the mixture combining a powerful germicidal andanalgesic action.

In its process aspect, the invention includes mixing at least one of theabove listed materials with a wetting liquid comprising a low meltingpoint binder or solvent, coating a dental floss therewith, and allowingsaid coating to cool and solidify or to dry.

DESCRIPTION OF BEST MODE OF THE INVENTION

The floss used herein can be made of conventional floss material such asflexible plastic, nylon, polyethylene, polypropylene and the like.Accordingly there is no need to illustrate same. The active/prophylacticmaterial is a phenol derivative/compound germicidal material typicallyselected from the group of synonyms generally known and consisting of4-hexylresorcinol; or 1,3-benzenediol,-4-hexyl or alternatively sodiumphenolate.

The binder for fixing the above material onto the floss is a non-toxic,sterile, low melting material such as microcrystalline wax; preferablyone that softens at mouth temperature. In the process of making thefloss, the binder is melted and the active/prophylactic material isdissolved therein in a suitable receptacle. The thread or floss isdispensed from a spool thereof and passed through the hot coatingmixture. The coated thread is allowed to cool. Thereby forming at leastan external coating on the floss. The amount of active material in thecoating can be varied according to desired end use. Thus, to make afloss intended for use in a regular maintenance program, the coatingmixture can contain from 0.001 to 25 percent by weight of activematerial, the remainder (75%) being binder. For use as needed in thecontrol of minor infections in the gum tissues, the concentration of thecoating will range from 25 to 75 percent by weight, the remainder beingbinder with the exact amount also dependent on the binder's properties,and, in particular, the solubility of the active material therein.

In operative use, the floss of the invention is inserted into thecrevices or spaces between the mouth teeth and then is pulledtherethrough. Thus, the active material is wiped off the floss and ontothe dental crevice surfaces and gums thereby treating the same andinhibiting germ growth there and the like. Suitably, the floss may becoated in a device of the type shown in U.S. Pat. No. 3,830,247.

The invention contemplates the following alternative methods of applyingthe active ingredient to the floss.

Another method of waxing is by preparing a solution of wax in a volatilesolvent subsequently evaporated out.

The wax may alternatively be applied as a aqueous emulsion.

As an alternative to bathing the unwaxed floss in a bath of liquid wax,the wax may be applied by metering rolls with a felt applicator suppliedwith liquid wax thereby to saturate the unwaxed floss passedtherebetween.

Where it is desired to avoid waxed floss, a soap or detergent mayinstead be used as a binder for the prophylactic material and applied tothe floss.

Alternatively, the floss may be impregnated with a mixture of a drygermicidal powder which has been diluted with a dry inert powder andsubsequently coated with a water-soluble cellulose derivative such asmethyl cellulose or sodium carboxymethyl cellulose as a binder.

As a further alternative, a water-soluble binder can be mixed with waterand the active/prophylactic (germicidal) ingredient. The floss is thencoated with such mixture.

Without further analysis, the foregoing will so fully reveal the gist ofthis invention that those skilled in the art can by applying currentknowledge thereto readily adapt if for various applications withoutomitting certain features which can constitute essential characteristicsof the generic or specific aspects of this invention. Therefore, a morelengthy description is deemed unnecessary.

It is intended that various changes may be made in this invention in thepractical development thereof, if desired. Such changes are comprehendedwithin the meaning and range of equivalency of the following claims. Theinvention, therefor, is not to be restricted except as is necessitatedby the prior art.

While certain novel features of this invention have been shown anddescribed and are pointed out in the annexed claims, it will beunderstood that various omissions, substitutions and changes in theforms and details of the instant invention illustrated and in itsoperation can be made by those skilled in the art without departing fromthe spirit of the invention.

What is claimed is:
 1. A method of making an improved dental flosshaving germicidal properties comprising the steps of forming a mixtureof dry germicidal powder consisting of a phenol derivative/compound anda dry inert powder, impregnating floss with said mixture andsubsequently coating the floss with a water-soluble binder of cellulosederivative and allowing said binder to dry on the floss to trap themixture thereon.
 2. The method of claim 1 wherein the mixture includesan aqueous solution of a water-soluble binder, permitted to dry aftercoating the dental floss with the mixture.
 3. The method of claim 1 inwhich the germicidal coating is 4-hexylresorcinol.
 4. The method ofclaim 1 in which the germicidal coating is sodium phenolate.
 5. Themethod of claim 1 where in the water soluble binder is methyl cellulose.6. The method of claim 1 where in the water soluble binder iscarboxymethyl cellulose.
 7. An improved dental floss made by the methodas recited in any of the preceding claims.